I have specified the thermal phase change model for mass transfer in CFX-Pre, but the box for the saturation temperature is not appearing.

If you define a homogeneous binary mixture which contains the same materials you are using in your fluid pair the saturation temperature is defined by the binary mixture and does not need to be set on the fluid pairs form. If you delete the binary mixture or use different fluids in your domain definition then the saturation temperature will appear on the fluid pairs form.

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